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Casing and Tubing for Sour Oil and Gas Service

In order to prevent possible sulfide stress corrosion cracking in sour gas and oil wells containing H2S, it is necessary to use specially manufactured tubing and casing. API 5CT Group 2 grade tubing and casing have been developed and used widely for this purpose. However these may not be adequate in high concentration of H2S.

To address this, Sumitomo Metal, after years of research and development, has succeeded in developing improved materials with higher strength and higher corrosion resistance for casing and tubing.

These are available in our SM-S series as shown below.

Sumitomo Metals does not recommend SM sour series greater than 110ksi grade for tubing applications.

Each of these grades is produced with rigid manufacturing controls covering chemical composition, heat treatment (quenching and tempering), tensile property, hardness and microstructure

Type
Grade
Mechanical Characteristics
Quality Control
Yield Strength
Tensile Strength
HRC
Hardness
Min.
tempering temp.
SSC test * (1)
Min.
Max.
Min.
Max.
(oF)
NACE TM0177 Methode-A
API
L80
80
95
95
23.0
1050
-
C90
90
105
100
25.4
1150
80%SMYS
(1atmH2S, Solution-A)
T95
95
110
105
25.4
1200
80%SMYS
(1atmH2S, Solution-A)
Sour Service
SM-80S
80
95
95
23.0
1150
90%SMYS
(1atmH2S, Solution-A)
SM-90S
90
105
100
25.4
1150
90%SMYS
(1atmH2S, Solution-A)
SM-95S
95
110
105
26.0
1150
90%SMYS
(1atmH2S, Solution-A)
SM-95TS *(2)
95
110
105
26.0
1150
85%SMYS
(1atmH2S, Solution-A)
High Strength Sour Service
SM-C100
100
115
105
27.0
1100
85%SMYS
(1atmH2S, Solution-A)
SM-C110
110
125
115
30.0
1100
85%SMYS
(1atmH2S, Solution-A)
High Strength Mild Sour Service
SM-110S
110
125
115
30.0
1100
85%SMYS
(0.1atmH2S, Solution-B)
SM-110TS *(2)
110
125
115
30.0
1100
85%SMYS
(0.1atmH2S, Solution-B)
SM-125S
125
140
130
36.0
1050
85%SMYS
(0.03atmH2S, Solution-B)

*(1) SSC test of methode-B & methode-D is available on request
*(2)
Collapse and sour


CHARACTERISTICS

1.Materials

The chemical compositions have been carefully determined to provide resistance to sulfide stress corrosion cracking as well as to insure complete through wall hardening.

2. Heat Treatment

Quenching and tempering are conducted under rigid temperature control to assure homogeneous physical properties and micro structures.
New Higher Strength Sour Resistant Grades SM-110S, SM-C100, SM-C110, SM-125S have been developed.

3. Micro Structure

These grades exhibit fully tempered martensite which is considered to be the most desirable for resistance to sulfide stress corrosion cracking.

4. Tensile Properties and Hardness

Yield strength is limited within a narrow range and hardness is controlled to within the predetermined maximum limit.

5. Sulfide Stress Cracking (SSC) Performance

SM sour resistant grades are designed for 85% or 90% SMYS in NACE condition or equivalent method such as Sc value (ex.Sc value).
Excellent SSC resistance has been achieved through rigorous, chemical composition, heat treatment, microstructure, tensile properties, hardness and so on.

View Graphs on the Next Page

 


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